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8-1d 8-1d-1

The polymerization of a 1,3-diene such as 1,3-butadiene, isoprene, and chloroprene can lead to cis and trans isomers when polymerization occurs by a 1,4-polymerization. On the

other hand, 1,2-polymerization through one or the other double bond can yield isotactic, syndiotactic, or atactic polymers, for example, for 1,3-butadiene

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During the first decade of the eighteenth century, these higher wartime interest rates continued A rate of 7% is mentioned on private credits, and more rentes were created at 81 3% (400) Thereafter rates declined, and for much of the century a range in quiet times of 4 5% prevailed on good private credits and 5 6% on loans to the State (400) In 1766 a law sought to lower the legal rate for private credits from 5 to 4%, but it was not obeyed In addition to these general statements about interest rates in eighteenth-century France, there are some more precise data on interest rates at specified dates In 1710 all the rentes were converted to a 5% basis (402) This was a wartime forced conversion; the 81 3% rate previously quoted is probably a better guide to the market.

8-1

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The situation is exactly analogous to the polymerization of monosubstituted alkenes; the var ious polymer structures would be those in Fig. 8-1 with R CH2 . With chloroprene CH and isoprene, the possibilities are enlarged since the two double bonds are substituted differently. Polymerizations through the 1,2- and 3,4-double bonds do not yield the same product as they would in 1,3-butadiene polymerization. There are, therefore, a total of six structures possible corresponding to isotactic, syndiotactic, and atactic structures for both 1,2- and 3,4-polymerizations; for instance, for isoprene, one has the situation shown in Eq. 8-2 with polymers V and VI capable of exhibiting the structures in Fig. 8-1 with R CH2 CH CH2 and C(CH3 ) CH2 , respectively.

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During 1713 1715 the payments on some rentes were arbitrarily cut to 4% (402) In 1718 the funded debt was unified at 4% (400) In 1720, at the height of the Mississippi boom, when many rentes were being turned in for stock, their rate was again cut briefly to 2 21 2% (402) This was peacetime It was also the period when the English were bringing the rates on their funds down from 6 to 3% Evidently the ideas behind Dutch finance were spreading through Europe The French experiment, however, did not enjoy the firmer political and economic foundations that existed in Holland and England While Law s bank was exchanging its stock and its bank notes freely for government securities, an initial decline in interest rates occurred, but this episode lasted only a very few years.

8-2

8-1d-2

From the practical viewpoint, the more important products from 1,3-dienes are those that occur by 1,4-polymerization of the conjugated diene system, for example, for isoprene, we obtain

Quotations for rentes during the collapse of the boom in 1720 1721 would be interesting, but have not come down to us Around 1735, however, the Church and the Chamber of Commerce of Marseilles both borrowed at 5%, and the government created new 5% rentes without compulsion (400) In 1749 the first bearer rentes were created; these were at 5% In spite of the many vicissitudes of the century, very high yields on rentes were not quoted until after the revolution There is evidence of persistent saving by the rentiers and a demand for safe investment Five percent seemed to be the magic rate throughout most of the seventeenth and eighteenth centuries Lower and higher rates proved to be temporary In 1756, when the Seven Years War began, the government created a huge volume of new 5% rentes and apparently sold them without coercion.

8-3

Open It Up!

1,4-Polymerization leads to a polymer structure (VII) with a repeating alkene double bond in the polymer chain. The double bond in each repeating unit of the polymer chain is a site of steric isomerism since it can have either a cis or a trans con guration. The polymer chain segments on each carbon atom of the double bond are located on the same side of the double

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javascript pdf preview image

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how to print pdf file without preview using java

how to print pdf file without preview using java

javascript pdf preview image

javascript pdf preview image

javascript pdf preview image

javascript pdf preview image

how to print pdf file without preview using java

javascript pdf preview image

how to print pdf file without preview using java

javascript pdf preview image

how to print pdf file without preview using java